KIP-Veröffentlichungen

Jahr 2010
Autor(en) Andreas Reiser, Gernot Kasper, Catalin Gainaru, Roland Böhmer
Titel High-pressure dielectric scaling study of a monohydroxy alcohol
KIP-Nummer HD-KIP 10-23
KIP-Gruppe(n) F3
Dokumentart Paper
Quelle J. Chem. Phys. 132(2010) 181101
Abstract (en)

Glass forming monohydroxy alcohols show an exponential Debye-type dielectric relaxation, which proceeds slower than the structural relaxation. Dielectric high-pressure measurements of 2-ethyl-1-hexanol reveal that isochronal scaling is violated. Temperature-volume scaling was found to be valid separately for the Debye-type and for the structural relaxation, yielding a scaling exponent of γ=1.8

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