KIP publications

year 2006
author(s) Andreas Reiser, Gernot Kasper
title On the pressure dependence of fragility
KIP-Nummer HD-KIP 06-34
KIP-Gruppe(n) F3
document type Paper
Keywords (shown) glass transition, high pressure, dielectric loss and relaxation
source Europhys. Lett. 76 (2006) 1137
Abstract (en) We have investigated the fragility of glycerol, propylene carbonate, and meta-fluoroaniline at pressures up to 700 MPa using dielectric spectroscopy. All three small-molecule glass formers do not show a pressure dependence of fragility within experimental error. The ratio of glass transition temperature and Vogel-Fulcher-Tammann temperature is pressure independent. The results are discussed in the frame of the defect diffusion model.
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